This paper proposes a modified configuration of single-phase Pack U-Cell (PUC) multilevel inverter in which the output voltage has higher amplitude than the maximum DC link value used in the topology as a boost operation. The introduced inverter generates seven-level AC voltage at the output using two DC links and six semiconductor switches. Comparing to cascaded H-bridge and neutral point clamp multilevel inverters, the introduced multilevel inverter produces more voltage levels using less components. The proposed inverter is used in PV system where the green power comes from two separate PV panels connected to the DC links through DC-DC converters to draw the maximum power. Due to boost operation of this inverter, two different PV panels can combine and send their powers to the grid. Simulations and experimental tests are conducted to investigate the good dynamic performance of the inverter in grid-connected PV system.